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Chemical Recycling

Chemical Recycling

patagonia jacketAnother way to recycle plastics, is chemically.

Here plastics are actually dissolved back into their original chemical components. These are then cleaned up and reused to make new plastics which, it is claimed, are as good as the original. At present it is a limited, expensive and problematic solution and can’t be applied to all plastics. Even so, it is already being employed by some companies.

Patagonia, for example, are using it in their Capalene base layer and fleeces. You can wear them them and then recycle these articles of clothing through their recycling program. It’s a very interesting scheme – read more about it here.

Other ways to recycle and reuse plastic trash here

Recycling and  waste plastic – a discussion

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Fulmers full of plastic…

Commissioned by the Netherlands Ministry of Infrastructure and the Environment, IMARES has published its new monitoring report on quantities of plastics in stomachs of Northern Fulmars found on Dutch beaches up to year 2013.

Currently, 94% of investigated stomachs of Dutch Fulmars contained one or more plastic particles, and about 52% contained more than the critical level of 0.1 gram plastic. North Sea governments have set a policy target where this percentage is reduced to below 10%.

Dear all    /   beste allemaal

We have recently published a new IMARES-report, updating our time series of Fulmar plastic ingestion monitoring in the Netherlands. The link to a full download of the report (and a range of other issues) can be found at the familiar dossier site www.wageningenur.nl/plastics-fulmars .  We hope this will stimulate the continued support from all those people surveying beaches and other co-workers! Without such help, this sort of study would be impossible, so thank you all very much!

 

With thanks to Fabiano of Global Garbage

 

 

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Definitions

Don’t know your PETS from your pug. Think Polymer is a girl’s name? Check out this collection of definitions essential for understanding plastic!

What is plastic -an introduction here

Plastics – a big list of different plastics

There is a new machine on the market that can create 3d components out of plastic without the need for moulds. Using plastic thread and computer design drawings (or even a ...
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Is a persistent, bioaccumulative and toxic chemical - ie one that lasts a long time, accumulates in the food chain and is, well, toxic. Read more here... Humans absorb  antimony  from ...
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So most plastics are made from oil and most plastics do not biodegrade. See how and why here... But what does that actually mean? Biodegrading Biodegradation refers to the breaking down ...
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Bioplastics or organic plastics are derived from renewable sources such as starch, vegetable oil and even chicken feathers. Some plant derived plastics biodegrade, some do not. The term bio-plastics is used to ...
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Bisphenol A or BPA is it is known to its chums is used in some thermal paper products such as till receipts. the epoxy plastic liners found in many cans and tins, polycarbonate plastics ...
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Quick Introduction Cellophane is made from cellulose It is biodegradable However the way it is made results in a lot of other kinds of pollution Cellophane bags were often used to ...
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Plants and animals are organic everything else is inorganic Inorganic things are made from chemicals. Chemicals are also found in organic things too. Confused yet? All matter contains chemicals - either single chemicals, ...
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Plastic was the name given to early synthetic products such as cellophane,  that were derived from cellulose. These plastics  were biodegradable. Then they learnt how to make similar products from oil. Or ...
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So most plastics are made from oil and most plastics do not biodegrade. See how and why here… And yet you will find plastics described as degradable biodegradable compostable What do these ...
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Traditional plastics do not biodegrade. Of course plastic breaks, tears and cracks. It weathers and sunlight makes it brittle, It falls apart – it degrades – but only into smaller pieces of ...
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The chemical name for dioxin is: 2,3,7,8- tetrachlorodibenzo para dioxin (TCDD). The name "dioxins" is often used for the family of structurally and chemically related polychlorinated dibenzo para dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). Certain ...
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Copied from the The EU list of potential endocrine disruptors The EU strategy for endocrine disruptors includes the task of compiling a candidate list of potential endocrine disruptors. The list prioritises ...
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A few quotes on the endocrine system....... "Although we rarely think about them, the glands of the endocrine system and the hormones they release influence almost every cell, organ, and function ...
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To understand plastic you need a lot of time and a good working knowledge of chemistry at the very least. Currently I am trying to find out what epoxy resin actually ...
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Ethane is a chemical compound in the form of a colorless, odorless gas . It is one of the by products of oil refining. It can be isolated from natural gas, ...
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Index Natural fibres for rope, string, sacking, industrial uses, delicate fabrics and yarn HERE Synthetic fibres Read more HERE Regenerated Fibres Read more HERE Yarns String for tying - find natural ...
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Hydrocarbon is a molecule that only contains hydrogen and carbon atoms, joined together by covalent bonds. Remember that a covalent bond is a shared pair of electrons. These compounds may be simple with ...
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Methane is a short-lived climate pollutant with significant climate warming potential. Methane gas, or biogas, is released  when organic material breaks down. But only when organic materials are so compacted there ...
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Micro plastics are microscopic or very small pieces of plastic that can be found in soil, water even in the air. They are too small to collect or clean up so ...
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We are going to start right at the beginning – before plastic there were polymers - before polymers it was monomers.. A monomer is a molecule that can join with other molecules ...
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Crude oil is a mixture of different hydrocarbons each with a different boiling point. These substances are separated from each other  in a distillation tower. This results in the separation of heavy crude ...
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Nylon is often associated with the fabric of the same name but can be used to make all manner of things from fibre to  moulded objects. Different nylon types are known ...
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Don't throw those sweet wrappers away you may need them to run your car. They can be turned into oil by Thermal depolymerization (TDP) or Pyrolysis System. Thermal Depolymerization  is the thermal decomposition ...
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Polyethylene terephthalat frequently shortened to PET or PETE and was formerly called PETP or PET-P. It is an ethane derived plastic. PET or PETE  (plastic code 1) is most often used for ...
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While I was in Malaysia I got to see some orangutangs. Most of them were in the rehabilitation center which is basically a safari park, a bit of preserved jungle.  I ...
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Perfluorochemicals (PFCs) are a family of man-made chemicals. They have been around since the 1950s. They include perfluorooctane sulfonate (PFOS; C8F17SO3), perfluorobutane sulfonate ( PFBS; C4F9C03), perfluorooctanoic acid (PFOA; C8F15O2H), perfluorobutanoic ...
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I was under the impression that pops was some kind of horrid Yorkshire dish involving hot milk and bits of bread but this is not the case. Rather POPs are a small ...
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are used as a plasticiser  used to make a material like PVC softer and more flexible. But they are also used in a wide range of other products. They are small ...
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Plastic codes are the numbers you find on the base of your shampoo bottle and the like. They  identify the type of plastic used to make the product. Only the most common ...
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Quick links List Of Links Quick Plastic Facts List Of Plastics  – the most common types of plastics, what they are used for and links to technical data sheets. Plastic Lifespan why most plastic ...
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are man-made organic chemicals; They are added to plastic,to make it flexible, resilient and easier to handle: They include endocrine disrupting and controversial phthalates: Claims as to the number of plasticisers out ...
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Plastics can be made in a variety of ways from a variety of materials; shale gas, oil, plants even chicken feathers can all be used to make plastic. However oil derived plastics ...
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Polychlorinated biphenyls (PCBs) are a group of manmade chemicals. They are oily liquids or solids, clear to yellow in color, with no smell or taste. PCBs are very stable mixtures that ...
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is the most common plastic. the annual global production of polythene is approximately 80 million tonnes. it is an ethane derived plastic. Ethane isone of the byproducts of oil refining. It can ...
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There are some truly biodegradable and compostable bioplastics. Biodegradable products break down through a naturally occurring microorganism into simple, stable compounds which can be absorbed into the ecosystem. More about biodegrading here. To ...
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Polymers A monomer is a molecule that can join with other molecules to form a chain of molecules. A chain of monomers (or molecules) is called a polymer.  Chains of polymers then bond or stick together to ...
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Polypropylene (PP) plastic code 5 It is the second most important plastic after polyethylene. It is a thermoplastic polymer that is rugged and unusually resistant to many chemical solvents, bases and acids. It ...
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Polystyrene is used to make coffee cups soup bowls and salad boxes foam egg cartons; produce & meat trays disposable utensils packing "peanuts" foam inserts that cushion new appliances and electronics television and ...
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Polyurethane is a general term used for a class of polymers derived from the condensation of polyisocyanates and polyalcohols. Polyeurothenes are are petrochemical-based derived polymer and (man) made like all the ...
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When I was young and innocent, I knew nothing of polytetrafluoroethylene (PTFE). Well, it's not the kind of thing a nicely brought up girl should have to deal with. Instead, I ...
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 A white brittle plastic until you add plasticisers the most common being phthalates then it becomes soft and flexible. PVC is known as the “poison plastic” because of the lethal chemicals produced ...
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This post is an introduction to recycling and reusing plastic non-biodegradable plastic at end of life. (also see Plastic Lifespan and Disposing Of Plastic ). They include Recycling Transformation Reuse Recycling, Transforming & Reusing ...
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There are two major categories of rubber; natural and synthetic. The most popular compounds are; Natural RubberVulcanised RubberSynthetic History Thousands of years BC Indians living in Central and South America were using ...
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Plastic? Rubber? Just plain weird? Used for everything  from ice-cube trays to adult toys to cake tins it certainly gets around. So what is silicone?? Silicon is a natural chemical element ...
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Plastics are divided into thermoplastics and thermoset plastics. Thermoplastics can be heated and shaped many times. Thermoplastics pellets soften when heated and become more fluid as additional heat is applied. The curing ...
Read More
Dotted around the world are  5 great trash vortexes. They are right out there in the middle of the sea and they are huge.  A "plastic soup" of waste floating in the Pacific Ocean ...
Read More

Find out more about plastic, the product – here

 

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Plastic in Plankton

Images of microplastic ingestion by plankton. From Cole, Matthew, et al. “Microplastic ingestion by zooplankton.” Environmental science & technology (2013).

plastic plankton

 

Laboratory studies that have shown ingestion in marine species.

Zooplankton: Cole et al. 2013
Invertebrates: Thompson et al. 2004; Besseling et al. 2013

 

 

And here it is on film

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Nappies, tampons and wet wipes – dirty!

Nappies

The liner or topsheet – made of the plastic polymer polypropylene – sits next to the baby’s skin and protects against wetness. From this layer, fluids flow down through the pulp-based tissue layer and into the core.

The core contains fluff pulp and SAP, an absorbent polymer to draw in and contain the baby’s urine and faeces.

Leakage from the nappy is minimised by a plastic bottom layer and the elastic barriers that hold the nappy around the child’s waist. The nappy is thrown away after it is soiled.

The average baby will go through 5,000 nappies. As 85 per cent of people are using disposables, they now form 4 per cent of all household waste, costing the taxpayer £40m each year to dispose of them.

Of the approximately eight million disposable nappies used in the UK every day, around 7.5 million end up in landfill sites.

Disposable nappies use three and a half times more energy than real nappies to produce, eight times more non-renewable materials and 90 times more renewable resources.The ecologist

7 million trees are cut down every year just to make disposable nappies Green Box Day

Menstrual Products

Along with cotton buds, tampons, applicators and panty liners make up 7.3 % of items flushed down the toilet in the UK.3

For every kilometre of beach included in the Beachwatch survey weekend in 2010, 22.5 towels/panty liners/backing strips, and 8.9 tampon applicators, were found.
According to the Sewer Network Action Programme, even products that are described as flushable or biodegradable can contribute to more than half (55%) of sewer flooding due to blockages in sewers.

In the UK alone, we buy more than 3 billion items of menstrual lingerie every year, spending £349 million in 2010 on sanitary and ‘feminine hygiene’ products.

About 90% of the materials used to make sanitary pads and liners are plastic and include polyethylene, polypropylene and polyacrylate super absorbents.

Every year, over 45 billion feminine hygiene products are disposed of somewhere.

Commercial production of superabsorbent polymers began in Japan in 1978 for use in sanitary pads. In the 80’s, using crude oil derived raw materials, European manufacturers enhanced the polymer so that it now absorbed 30 times it’s own weight under pressure. By the mid 90’s, production of SAP jumped to a massive 700 million tons. 75% used in diaper production, 10% in incontinence products, 10% in sanitary pads, and the rest in meat trays, etc.

Sources

natracare and womens environmental network

Items such as nappy liners, ‘flushable’ wipes and toilet seat liners cause many problems. But the main pest are women’s sanitary items.

The council says every single one has to be removed and sorted by hand by workers at waste stations.

Oh Yuck! Jesse Peach went to check out the undesirables in Wellington that haunt drains beneath our feet. Read more: 

Find out How to Menstruate Plastic Free here

plastic plankton
As we already know from this blog,tiny sea creatures, the bedrock of the food chain, ingest these micro plastics. You can see plankton hoovering up plastic here.  There is increasing evidence that this is not a healthy diet.

Best to cut back on synthetics especially  those items that may get get washed into the sea.

 

 

You can find out about natural fibres here

 

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Plastic, an introduction

Quick links

List Of Links


Quick Plastic Facts
List Of Plastics
 
 – the most common types of plastics, what they are used for and links to technical data sheets.
Plastic Lifespan why most plastic don’t biodegrade
Compostable plastics that biodegrade within a certain amount of time).
Compostable, degradable and or biodegradable plastic – find out here.
Thermoplastics and thermoset plastics – plastics that melt & plastics that don’t
Making Plastics
monomers and polymers
Oil Derived polymers  – how they are  made  see the process here.
Bio Plastics derived from plants see the process here 
Additives – Fillers and chemicals are added to the base plastic to give color, texture and other qualities.  Read up on them here
Reports & statistics  links to the latest reports on plastic

Blog INDEX

Welcome a quick introduction to everything
About Plastic  everything you need to know about plastic and somethings you wish you didn’t
Bad Plastic – why you need to cut your plastic consumption
Cut plastic – how to cut unnecessary plastic out of your life & meet the other people doing it.
Links & Projects –links to other plastic free people, the U.K. directory and out other projects
Us & The Boycott –About us the blog and the boycott rules
Site Map

Plastics – the key points

Plastics are  used to make everything from varnish to stockings, bottles to car parts by way of crisp packets and computers. They have revolutionized the world for the better but are now a major environmental pollutant. We use them everyday, for everything, even inserting it into our bodies. And yet we know very little about them.

This blog explores plastic the product, examines its impact and considers what we should and shouldn’t be using plastic for.

What is plastic?

Definition of plastic
If you look in the Oxford dictionary you will find plastic can be used to describe
substances or materials that “are easily shaped or moulded: ‘rendering the material more plastic’
1. 2.1 Offering scope for creativity:‘the writer is drawn to words as a plastic medium’
2. 2.2 Relating to moulding or modelling in three dimensions, or to produce three-dimensional effects:‘the plastic arts’
3. 2.3 (in science and technology) relating to the permanent deformation of a solid without fracture by the temporary application of force.
4. Artificial or unnatural: ‘a holiday rep with huge white teeth and a plastic smile’

But more commonly today it is used as a noun to refer to a “synthetic material made from a wide range of organic polymers such as polyethylene, PVC, nylon, etc., that can be moulded into shape while soft, and then set into a rigid or slightly elastic form: Oxford.
or Any of various organic compounds produced by polymerization, capable of being molded, extruded, cast into various shapes and films, or drawn into filaments used as textile fibres. Your Dictionary

So the term plastic was originally used to describe anything fluid, responsive capable of being molded or modelled; Clay could be plastic; sculpture could be described as plastic.

But more recently it has come to mean a certain type of product – a fluid, synthetic material that can be molded to make almost anything.

Are All Plastics The Same?

Plastic (when used to describe a product and not a quality) can be applied to  a huge range synthetic polymers with massively different qualities. They look different, they act different and  the general application of the term plastic to all plastic materials soon leads to confusion. Products such as varnish for example are not usually thought of as plastic. But some are.

But are all these different products basically made from the same stuff? No, even the base material can be a different product.

Plastic was used to describe the early first plastics derived from cellulose which were biodegradable. Later the same name was given the oil derived product. This was  made in a very different way and did not biodegrade. It is now applied to corn starch plastic which is made differently again, from plant starch and is certified compostable.

To conclude;
plastics can be made in a variety of ways from a variety of materials; shale gas, oil, plants even chicken feathers;
different plastics have very different qualities.

Currently non- biodegradable, oil derived plastics are the most commonly used and so we tend to ascribe their qualities to all types of plastic.
Which is of course incorrect not least because  most oil derived plastics do not biodegrade and last for centuries possibly for ever, while there are other plastics that are truly compostable with a lifespan of months.

It is important to know your different plastic types and their massively varied characteristics.
The sheer versatility of plastics make this a big task.

Check out A List Of Plastics for information on the individual kinds of plastic.

Lets get to know plastic! Key Points

Despite being lumped under the one, all-embracing name, not all plastics are the same..

Non-biodegradable and biodegradable plastics
Some plastics are compostable, (they biodegrade within a certain amount of time). 
Most are not biodegradable and last if not for ever, for a very long time. Read  the Plastic Lifespan to find out why and how.

N.B. Plastics can be described as compostable, degradable and or biodegradable. Which may seem clear but can be misleading. Some “biodegradable plastics” are oil derived plastics with a degrading initiator added to make them fall apart (degrade) more  quickly. Unlike compostable plastics they don’t always break down into harmless substances and may leave behind a toxic residue. Read more here

Thermoplastics or Thermoset?
You might also hear plastic being described as a thermoplastics or thermoset plastic.
Thermoplastics can be heated and shaped many times.
Thermoset plastics can only be heated and shaped once.

Made from?
Plastic can be made from pretty much anything from oil to chicken feathers….

How is plastic made?

Plastics are  created from single units, monomers, combined in a variety of ways. This process is called polymerisation. This is why plastics are also called polymers. And you often find the word poly used in the name i.e. polystyrene.

Building Blocks – Polymers & Monomers

A polymer is a chain  ( poly= many, mer = part) of  single units called monomers. 
Natural polymers occur in nature and can be extracted. They include silk, wool, DNA, cellulose, starch and proteins.
Synthetic polymers such as plastic are made by scientists and engineers. They too are extracted from natural resources BUT…. though the base material may be a natural product such as oil, the polymers derived from it are not.
To make synthetic polymers, the monomors are joined together in new ways, using heat and/or pressure and sometimes a catalyst.
Different combination of monomors result in different products and there are hundreds of different kinds of plastic.
Read more here – monomers and polymers.

Definitions
Don’t know your PETS from your hamster. Think Polymer is a girl’s name? Check out this collection of definitions essential for understanding plastic!

What Is Plastic Made From?

Obviously given the different products, there is no one answer – it would depend on the plastic type.
Plastic can be made from just about anything but the two main feed materials are oil and plants (bioplastics)

Currently nearly all plastics (and we are talking millions of tons each year) are made from ethane.

Most ethane is derived from oil but it can also be got from coal, gas and plants.

Oil Derived Plastic  
.. are cheap, so cheap they can be used to make one use throwaway products like plates and nappies in huge amounts.

Most oil derived plastics are resistant to chemicals, microrganisms and water. They don’t rot. They last for centuries possibly forever. Find out why most plastics don’t biodegrade here.
More are being made everyday.

How are oil derived polymers are made? You can see the process here.

Bioplastics

Bioplastics or organic plastics are derived from renewable sources such as starch, vegetable oil and even chicken feathers.

Some bioplastics are compostable and biodegradable. SOME ARE NOT.

For example:

Bioplastics can be made from ethane derived from plants. This is the same as ethane derived from oil. Both are  used to make PET plastic. PET plastic does not biodegrade.

PLA  is a  plastic derived from poly lactic acid that is a certified compostable plastic.

Different processes are used to make the various types of bioplastic. You can find links to technical information here. 

Plastic Types

There are thousands of different types of plastic product with different qualities. Some of those differences are down to the polymers, a lot are a result of later addatives.

The first stage in plastic production is the polymerization of raw material. Then substances such as fillers and chemicals are added to give color, texture and a whole range of other qualities. Reinforcing fibers for example make the base polymer stronger while man-made organic chemicals, such as phthalates are added to make plastic flexible, resilient and easier to handle.

While the polymers used in base plastics are considered harmless, the potential toxicity of the many additives is often unknown and some are thought to be dangerous. 

Find out more about additives fillers and plasticizers here.

Plastic Lifespan
Perhaps the most amazing thing about most plastics is that they don’t rot. While every other thing on the planet is decomposing, plastic remains unchanged. Find out why most plastics don’t biodegrade here.

A List Of Plastics 

The most common types of plastics, what they are used for and links to technical data sheets.

Bad Plastic

Problems with plastic Whats not to like?

Interesting  Check out this  great post by Chris Woodford

List Of Links


Quick Plastic Facts
List Of Plastics
 
 – the most common types of plastics, what they are used for and links to technical data sheets.
Plastic Lifespan why most plastic don’t biodegrade
Compostable plastics that biodegrade within a certain amount of time).
Compostable, degradable and or biodegradable plastic – find out here.
Thermoplastics and thermoset plastics – plastics that melt & plastics that don’t
Making Plastics
monomers and polymers
Oil Derived polymers  – how they are  made  see the process here.
Bio Plastics derived from plants see the process here 
Additives – Fillers and chemicals are added to the base plastic to give color, texture and other qualities.  Read up on them here
Reports & statistics  links to the latest reports on plastic

Blog INDEX

Welcome a quick introduction to everything
About Plastic  everything you need to know about plastic and somethings you wish you didn’t
Bad Plastic – why you need to cut your plastic consumption
Cut plastic – how to cut unnecessary plastic out of your life & meet the other people doing it.
Links & Projects –links to other plastic free people, the U.K. directory and out other projects
Us & The Boycott –About us the blog and the boycott rules
Site Map

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Cardboard laminated

When I started my boycott I soon realized that giving up plastic would be no easy ride but I didn’t really know just how insidious plastic was. In my ignorance I made mistakes. For instance I thought shiny cardboard was shiny because, oh I don’t know, it had been varnished or something. It wasn’t until I put some in the compost heap and saw it disintegrating into separate components that I discovered it was covered with a thin layer of plastic.

Why? The plastic strengthens the base material, makes it waterproof and protects any printed design work

Examples of laminated card include business cards, labels on clothes for sale and some  food containers.

More

and don’t forget , paper and card can also be plastic lined to make waterproof containers. Those paper cups are not just paper. Sigh.

Find other sneaky plastics here….

Ethane derived plastics

Ethane is a chemical compound in the form of a colorless, odorless gas .

Its chief use is as feedstock for ethylene production.
Ethane is treated (cracked) to make ethylene.

Ethylene is used to make.

Polyethylene (Polythene)

Ethylene is one of the raw materials used to make polyethylene (abbreviated PE) (IUPAC name polyethene or poly(methylene))This is the most common plastic.The annual global production of polythene is approximately 80 million tonnes.

    • High-density polyethylene (HDPE)
    • Cross-linked polyethylene (PEX or XLPE)
    • Medium-density polyethylene (MDPE)
    • Linear low-density polyethylene (LLDPE)
    • Low-density polyethylene (LDPE)
    • Very-low-density polyethylene (VLDPE)

PVC polyvinyl chloride

Ethylene and chlorine are raw materials for PVC. Ethylene is chlorinated then cracked to make the  vinyl chloride monomer (VCM). Nearly all VCM is used to make polyvinyl chloride

polystyrene (PS)

Ethylene is  reacted with benzene to make ethylbenzene which is further processed into styrene. The main outlets for styrene are polymers and synthetic rubbers such as polystyrene,acrylonitrile-butadiene-styrene (ABS) and styrene butadiene rubber (SBR).

Other Plastics

Ethylene can be oxidised to create ethylene oxide This mostly  used to make ethylene glycol, from which polyester fibres for textile applications, PET resins for bottles and polyester film are made.

Recycling & Biodegradability

These plastics do not biodegrade.

They can be recycled.

Other Uses

ethylene oxide is a poison gas. It is highly flammable and explosive.

It can be used to make weapons

The gas leaves no residue on items it contacts, so can be used  instead of  steam in the sterilization of heat-sensitive tools and equipment, such as disposable plastic syringes.

Other ethylene derivitives are  found in in shampoo, kitchen cleaners, personal care products, etc

A few statistics

Global ethylene production was 107 million tonnes in 2005,[4] 109 million tonnes in 2006.[14] NNFCC Renewable Chemicals Factsheet: Ethanol, 138 million tonnes in 2010 and 141 million tonnes in 2011.[15] By 2010 ethylene was produced by at least 117 companies in 55 countries.[16] To meet the ever increasing demand for ethylene, sharp increases in production facilities are added globally, particularly in the Mideast and in China.[16]

In Abu Dhabi, the Borouge III ethane cracker which will produce 1.5m tonne/year of ethylene is expected to start up 2014.

In Mexico Braskem and Grupo Idesa’s $2.5bn 1m tonne/year ethylene XXI project  is expected to start up in 2015.

Useful Links

Polyethylene (Polythene)

PVC polyvinyl chloride

polystyrene (PS)

PET resins

Wikkipedia  and again

Icis.com market data

Other Plastic Info

Find out about other types of plastic here

Don’t know your crack from you cracking – try this introduction to plastic

 

 

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Reports & Statistics Index

Post Index

Wasting Away – how much rubbish do we create globally
Definitions You can find definitions, clarifications and explanations here

Number CrunchingFor nasty stats go to  Statistics
Reports

Find all reports here  or by look by category below.

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For the latest news, reports on and about plastic plus statistics to shame any one who still thinks disposable carrier bags are a good idea!

Check out these scary stats: Wasting Away – how much rubbish do we create globally

Definitions

Don’t know your P.E.Ts from your pets? You can find definitions, clarifications and explanations here

Number Crunching

“Our previous work had suggested that bottled water production was an energy-intensive process, but we were surprised to see that the energy equivalent of nearly 17 million barrels of oil are required to produce the PET bottles alone,” Cooley told PhysOrg.com.

For more nasty stats go to  Statistics

Reports

Check out the latest scientific reports on plastic and the effects it is having on everything from plankton to elephants

Find all reports here  or by look by category below.

And the latest new reports as rounded up by Fabiano of www.globalgarbage.org are here. Thank you for all his hard work.

By Category

How much does plastic cost us

Everlasting Litter & Plastic Pollution

Seas Of Rubbish

Micro plastic trash 

Plastic and Animals

Chemicals in plastics 

People Who Know

Expert Opinions from people who have studied the subject and kindly submitted guest posts in People Who Know.

All Reports

Marine debris ingestion by coastal dolphins:

What drives differences between sympatric species?,

This study compared marine debris ingestion of the coastal dolphins Pontoporia blainvillei and Sotalia guianensis in a sympatric area in Atlantic Ocean.

Among the 89 stomach contents samples of P. blainvillei, 14 (15.7%) contained marine debris. For S. guianensis, 77 stomach contents samples were analyzed and only one of which (1.30%) contained marine debris.

The debris recovered was plastic material: nylon yarns and flexible plastics. Differences in feeding habits between the coastal dolphins were found to drive their differences regarding marine debris ingestion. The feeding activity of P. blainvillei is mainly near the sea bottom, which increases its chances of ingesting debris deposited on the seabed. In contrast, S. guianensis has a near-surface feeding habit.

In the study area, the seabed is the main zone of accumulation of debris, and species with some degree of association with the sea bottom may be local bioindicators of marine debris pollution.

Ana Paula Madeira Di Beneditto, Renata Maria Arruda Ramos,

(http://www.sciencedirect.com/science/article/pii/S0025326X14002008)

 

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Endocrine disruption, fish & polyethylene

Early warning signs of endocrine disruption in adult fish from the ingestion of polyethylene with and without sorbed chemical pollutants from the marine environment,

Abstract: Plastic debris is associated with several chemical pollutants known to disrupt the functioning of the endocrine system. To determine if the exposure to plastic debris and associated chemicals promotes endocrine-disrupting effects in fish, we conducted a chronic two-month dietary exposure using Japanese medaka (Oryzias latipes) and environmentally relevant concentrations of microplastic (< 1 mm) and associated chemicals. We exposed fish to three treatments: a no-plastic (i.e. negative control), virgin-plastic (i.e. virgin polyethylene pre-production pellets) and marine-plastic treatment (i.e. polyethylene pellets deployed in San Diego Bay, CA for 3 months). Altered gene expression was observed in male fish exposed to the marine-plastic treatment, whereas altered gene expression was observed in female fish exposed to both the marine- and virgin-plastic treatment. Significant down-regulation of choriogenin (Chg H) gene expression was observed in males and significant down-regulation of vitellogenin (Vtg I), Chg H and the estrogen receptor (ERα) gene expression was observed in females. In addition, histological observation revealed abnormal proliferation of germ cells in one male fish from the marine-plastic treatment. Overall, our study suggests that the ingestion of plastic debris at environmentally relevant concentrations may alter endocrine system function in adult fish and warrants further research.

Keywords: Plastic debris; Endocrine disruption; Japanese medaka; Germ
cells; Gene expression

Chelsea M. Rochman, Tomofumi Kurobe, Ida Flores, Swee J. Teh,

September 2014, Pages 656-661, ISSN 0048-9697,
http://dx.doi.org/10.1016/j.scitotenv.2014.06.051.
(http://www.sciencedirect.com/science/article/pii/S0048969714009073)

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PVA plastic

Here is an oil derived plastic that actually dissolves in water, is biodegradable and has been certified compostable. Interesting stuff.

The following is a collection of information that really needs to be properly collated.

Poly(vinyl alcohol) (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula [CH2CH(OH)]n. It is used in papermaking, textiles, and a variety of coatings. It is white (colourless) and odorless. It is sometimes supplied as beads or as solutions in water.[2] wikkipedia

PVA is produced through multiple chemical reactions. However, the starting compound is ethylene gas. So, where does ethylene gas come from? Well it is actually produced by some plants when their fruit ripens. It can also be produced from ethanol. These methods are just too expensive for commercial production. So, it’s made from you guessed it oil. However, it is able to be broken down by some types of bacteria making it biodegradable.

PVA (Polyvinyl alcohol) the plastic that’s afraid of water

This is to confirm that Flushpuppies pet-waste bags are produced by BPI-approved manufacturers from BPI-certified materials. These products are authorized to carry the BPI Compostable Logo (shown on the right) because they meet all of the requirements
of ASTM D6400 or ASTM D6868: they will disintegrate and biodegrade swiftly and safely in a professionally managed composting facility and not leave behind any non-compostable residues. http://flushpuppies.com/wordpress/wp-content/uploads/2015/03/2014-New-BPI-letter-Flush-Puppies.pdf

PVA films are used for packages that release their contents upon contacting water. Some brands of sanitizers, dyes, and detergents are packaged in dissolving plastic bags. PVA film has recently found a new use in agriculture. At high concentrations, some pesticides and herbicides can be toxic to humans. Farmers typically purchase concentrated chemicals, then mix them with water to prepare the dilute solutions that are applied to crops. Powdered insecticides and herbicides prepackaged in PVA bags are simply dropped into a container of water, and the farmer is never exposed to the powder. http://www.borlik.org/wp-content/uploads/2015/08/Dissolving-Plastic.pdf

Uses

Polyvinyl alcohol laundry bags are used in hospitals to minimize the contact hospital workers have with contaminated clothing and bedding. Dirty items are put into these special bags, which are then placed directly into the washing machine. Because polyvinyl alcohol is soluble in water, the bags dissolve and are washed down the drain with the dirty water. At the completion of the washing cycle, the clean clothes are removed from the washing machine

This was taken from a website selling the product.

Environmental Friendly characteristic
It has no any bad effect on environment. Once PVA is dissolved in water, specific microorganism will cause it to degrade. When treated with activated sludge, solutions of PVA will be decomposed into water and carbon dioxide.

Water solubility

1.Solubility is related to PVA film’s thickness and temperature. According the time of dissolving, the film has three types, quick, middle, difficult, all depend on its thickness and water temperature. Thicker film makes slow dissolving, high temperature makes fast dissolving.
Water soluble pva film can prevent operators from contacting toxic materials directly.It is safer and more convenient.

Water content

Water content of the water-soluble PVA film can change with environmental humidity. The water-soluble PVA films are usually sealed with the PE film to keep its water content invariable. After the water-soluble PVA films is taken out of the PE film, water content can vary from environmental humidity, whose property also varies with it.

Good gas barrier properties

Water-soluble PVA film has an excellent gas barrier to oxygen, nitrogen, hydrogen, helium, argon, carbonic acid gas and so on when the humidity is low, but it permit moisture and NH 3 to penetrate . Moreover, it has an excellent fragrance preservation of the contents and can keep products moisture and fresh as well.

Good antistatic properties

Because water-soluble film has a lot of hydroxyl groups in molecule, it does not take charges. It is different from the film that is made from the other synthetic resins and it has the same antistatic properties as cellophane. If PVA film is used for product packing, it could keep products out of dust.

Good printability

Water-soluble PVA film has the h3 polarity and the excellent printability so as to gravure print is beautifully completed without spark-treatment. Presently it has been widely used in the field of special printing, for example, water transfer printing.

Strength and Weathering resistance

PVA film has good tenacity, biaxial tension-strength and anti-tearing strength that ranks high among all kinds of films, flexing resistance is 10 times to other films. It has excellent Weathering resistance and service life is very long.

Good heat sealability and adhesiveness

Water-soluble PVA film has an excellent gas barrier to oxygen, nitrogen, hydrogen, helium, argon, carbonic acid gas and so on when the humidity is low, but it permit moisture and NH 3 to penetrate . Moreover, it has an excellent fragrance preservation of the contents and can keep products moisture and fresh as well.

Resistance to oil and chemicals

The Water-soluble PVA film has the good characteristic to resist the oils and fats such as animal oils, vegetable oils, mineral oils, fats, organic solvents and the hydrocarbons to penetrate. However, it can be affected by h3 acid, h3 base, chlorine free radical and some special chemical which can react with PVA such as borax, boracic acid and coloring matter and so on, so it isn’t fit for packing the above things.