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Isopropyl Alcohol

Isopropyl alcohol, or isopropanol (also known as rubbing alchohol or surgical spirit) is made from propene derived from fossil fuels and water.

Ethanol or ethyl alcohol is the stuff that makes you drunk and is made by fermenting

Isopropyl alcohol, or isopropanol

In 1920, Standard Oil Company (later Exxon) scientists in Linden, New Jersey, were trying to invent useful products from gasoline by-products. They produced isopropyl alcohol, or rubbing alcohol. Isopropyl alcohol was the first commercial petrochemical (chemicals made from oil) ever made and became the new ExxonMobil Chemical Company’ first product.

It is also known as rubbing alchohol and surgical spirit

Isopropyl alcohol is made from propene (which is derived from fossil fuels) and water. They are combined using a process called hydration.

During hydration, the component substances of water, which are hydrogen and oxygen (H20), react with those that compose propene—carbon and hydrogen (C3H6). The reactions form new chemical bonds and create isopropyl alcohol (C3H7OH). Read more here.

It has a wide range of uses

  • in disinfecting pads,
  • When used properly, it kills a significant number of bacteria and other potential contaminants, which is why it’s also used as a hand sanitizer in labs and hospitals.
  • as an antiseptic for cuts and scrapes.
  • to clean dirt from computer and electronic equipment. ” Since it evaporates almost immediately, there is little risk of shock or damage to electrical components, and it can even be used to clean the lasers in CD and DVD drives.”
  • removes  glue residue and dried ink,
  • remove stains from most natural fibers, including cotton, silk, and wool.
  • can be used as a de-icer.
  • to clean the glass.
  • removes wax or polish residue.

All the above was taken from Wise Geek. You can read more here.

It is a very useful multitasking product and you might want to consider keeping a bottle handy. You can buy it on line. I have never done so cannot tell you what the bottle is made from.

Or you may wish to explore the alternatives which are not petroleum based.

 

 

 

 

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Manufacturing Sodiums

In this post you can read about

  • Salt – (sodium chloride)NaCl
  • Glauber’s salt– (sodium sulphate). Synthesised from salt but also occurs naturally. A good laxative. Discovered by  Johann Glauber. Chemical formula Na2SO4.
  • Soda Ash/Washing soda – sodium carbonate. Synthesised from sodium sulphate but can also be obtained from the ashes of plants and natural deposits. Chemical formula Na2CO3.  
  • Bicarbonate of soda (sodium bicarbonateSynthesised from sodium sulphate but also occurs naturally. Chemical formula NaHCO3.
  • Caustic soda (sodium hydroxide)NaOH

Uses of sodium carbonate today

Overall, about 50% of the total production of sodium carbonate is used to make glass, 18% to make other chemicals and 10% in soaps and detergents.

Annual production of sodium carbonate

World 50 million tonnes
Europe 10 million tonnes
US 11 million tonnes
Russia 0.71 million tonnes1

Data from:
1.   Federal State Statistics Service: Russian Federation 2011

Manufacture of sodium carbonate

There are two main sources of sodium carbonate:
a) from salt and calcium carbonate (via the ammonia soda (Solvay) process)
b) from sodium carbonate and hydrogencarbonate ores (trona and nahcolite)

History 

Soda Ash

Plants

 Soda ash was called so because it was originally extracted from the ashes  of plants growing in sodium-rich soils, such as vegetation from the Middle East, kelp from Scotland and seaweed from Spain.

Soda ash or washing soda was originally made from the ash of of plants. The land plants (typically glassworts or saltworts) or the seaweed (typically Fucusspecies) were harvested, dried, and burned. The ashes were then “lixiviated” (washed with water) to form an alkali solution. This solution was boiled dry to create the final product, which was termed “soda ash;” this very old name refers to the archetypal plant source for soda ash, which was the small annual shrub Salsola soda (“barilla plant”).

The ashes of these plants were noticeably different from ashes of timber (used to create potash)

The plants  were harvested, dried, and burned. The ashes were then washed with water and boiled dry.

The final product the soda ash could be anything from 2 to 30% sodium carbonate.

It is obvious that extracting soda ash from plants was a limited and uncertain process.

Sodium carbonate (soda ash) and its derivatives were needed for the  manufacture of glass, textiles, paper, soap, and other products.

So the search began for a better source and a way of synthesising soda ash.

From Salt 

Le Blanc Method

In 1775 the French Royal Academy offered a prize to anyone who could develop a process for transforming common salt (sodium chloride) into soda ash (sodium carbonate).

Le Blanc won

The Leblanc process worked as follows

He reacted sea salt  (sodium chloride) with sulfuric acid in a reverberator furnace to form sodium sulfate.

Roasting the sodium sulphate with crushed limestone and coal  produced calcium sulfide. This could be further treated  to make 

  • Washing soda (sodium carbonate) used in the manufacture of glass.
  • Bicarbonate of soda (also known as sodium bicarbonate, sodium hydrogen carbonate, or sodium acid carbonate) used for many things

Sodium carbonate could then be treated to make caustic soda (sodium hydroxide) or lye which could be used to make soap.

Solvay Process

Was invented by the Belgian chemist Ernest Solvay (1838–1922) and patented by him 1861.

By 1913 the process was producing a large part of the world’s sodium carbonate.

Uses limestone, salt and ammonia..

Very basically, ammonia is added to a salt – like table salt. Carbon dioxide is bubbled through the solution producing sodium bicarbonate.

Sodium bicarbonate. is then heated and transformed into washing soda (sodium carbonate)

Hou’s Process

Long story short, Hou’s process is an upgradation of the Solvay process. The first few steps remaining the same, carbon dioxide and ammonia are pumped into the solution instead of limestone. Further, sodium chloride is added and this solution is left to saturate at 40ºC. It is then cooled to 10ºC and recycled to produce sodium carbonate. Ammonium chloride also precipitates in this process.

A refined version of the Solvay Process is still used today.

From Trona featured trona

Trona ore that is mined, then heated until it turns into soda ash also known as washing soda. Bicarbonate of soda is obtained through the same process

Large natural deposits found in 1938, such as the one near Green River, Wyoming, have made mining more economical than industrial production of washing soda in North America at least.

The USD 400m plant uses solution mining to extract the Trona-brine, a new process with high efficiency and large capacity for production.

Trona dates back 50 million years, to when the land surrounding Green River, Wyoming, was covered by a 600-square-mile (1,554-square-kilometer) lake. As it evaporated over time, this lake left a 200-billion-ton deposit of pure trona between layers of sandstone and shale. The deposit at the Green River Basin is large enough to meet the entire world’s needs for soda ash and sodium bicarbonate for thousands of years… Trona is mined at 1,500 feet (457.2 meters) below the surface. FMC’s mine shafts contain nearly 2,500 (4,022.5 kilometers) miles of tunnels and cover 24 square miles (62 square kilometers). Fifteen feet (4.57 meters) wide and nine feet (2.74 meters) tall, these tunnels allow the necessary equipment and vehicles to travel through them.” Read more: http://www.madehow.com/Volume-1/Baking-Soda.html#ixzz400Q1aQot

It is also mined out of certain alkaline lakes such as Lake Magadi in Kenya by using a basic dredging process and it is also self-regenerating so will never run out in its natural source.

And Turkey.

Eti Soda Inc. started production in 2009 at its new facility based in between Anakara and Istanbul in the Beypazari Trona Bed, the second largest known reserves of Trona in the world.

The Solvay method was the main way of obtaining of washing soda before the Wyoming trona deposits were discovered.  Now it is cheaper to mine Trona ore. In the U.S at least. The Solvay method is still used to manufacture tons of product.

There are claims that the Solvay method is less environmentally safe than mining and could cause serious waste management problems. On the other hand the mining process is accused of being heavily polluting.

Other Sources

Bicarbonate of Soda can be mined directly from the ground  as Nahcolite.

Caustic Soda The Leblanc and Solvay processes were eclipsed by new electrolytic methods for making chlorine and caustic soda.

More

You can find lots more uses, details of where to buy and information about the product listed here.

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How to find out if it’s toxic….

Polyethylene terephthalat PET or PETE plastic code 1  is made from carbon, hydrogen and oxygen, just like paper.

It is claimed that, just like paper, it can be safely burnt and will only produce carbon dioxide and water leaving no toxic residue.

I came across this nuggets out there in google land and as you know panning  in tham thar rivers often finds you only fools gold.

So lets see if I am richer than Midas or talking through my arsk no questions.

Google MSDS followed by the product name ie MSDS Polyethylene terephthalat

This pulls up the Material Safety Data Sheet for PET

Solid pellets with slight or no odor. Spilled pellets create slipping hazard. Can burn in a fire creating dense toxic smoke. Molten plastic can cause severe thermal burns. Fumes produced during melt processing may cause eye, skin and respiratory tract irritation.
Secondary operations, such as grinding, sanding or sawing, can produce dust which may present a respiratory hazard. Product in pellet form is unlikely to cause irritation
A useful guide for crafters on burning and melting plastic can be found here.

 

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Persistant Organic Pollutants

I was under the impression that pops was some kind of horrid Yorkshire dish involving hot milk and bits of bread but this is not the case. Rather POPs are a small set of toxic chemicals that remain intact in the environment for long periods and accumulate in the fatty tissues of animals.

POPs stands for persistent organic pollutants, also classed as PBTs (Persistent, Bioaccumulative and Toxic) or TOMPs (Toxic Organic Micro Pollutants.)

  • Persistant because they are are resistant to natural biodegradation. They do not break down and can last for decades.
  • Pollutants because they are highly toxic, causing death, disease, and birth defects among humans and animals.

plastic in fishHow can you avoid them? You cant! They travel through the environment through the atmosphere (windbourne), the food web (by being eaten) and through the waterways by attaching themselves to particles in water. POPs released in one part of the world can be transported many hundreds of miles away from the original source. POPs have been discovered in remote regions where they have never been used, the middle of oceans and Antarctica.

Pops can enter the food chain at the most basic of levels. “Planktonic organisms are the first link for pollutant transfer in the pelagic system. Traditionally, primary producers, (all those organisms that are able to synthesise organic matter capturing the energy of the sunlight) such asphytoplankton have been considered as the initial step for transport of POPs into food webs. Recent studies, however, point out that the capacity of uptake of bacteria is an important route for POPs transportation via the microbial food chain. The microbial food chain is the link between microorganisms in the sea.” From GPA website.

Because POPs are not soluble in water but readily absorbed and retained in fatty tissue of animals, this leads to a process called Biomagnification, also known as bioamplification or biological magnification. This is, is the increase in concentration of a substance that occurs in a food chain as a consequence of:

Food chain in a swedish lake. From the bottom:...

Food chain in a swedish lake. From the bottom: freshwater shrimp, bleak, perch, northern pike, osprey (Photo credit: Wikipedia)

  • Persistence (can’t be broken down by environmental processes)
  • Food chain energetics
  • Low (or nonexistent) rate of internal degradation/excretion of the substance (often due to water-insolubility)

Which means as POPs pass up the food chain, they increase exponentially. For example lets say that each bit of plankton contains 1 POP. A worm eats 5 plankton so now it contain 5 POB, 5 worms are in turn is eaten by a fish (25) and 3 fish are caught by a fisherman (75). The higher up the food chain the more you absorb.

It is claimed that plastic particles in the sea attract POPs.

Related articles

Where Do Pops Come From

Most are created by humans in industrial processes, either intentionally or as byproducts.

Many POPs are currently or were in the past used as pesticides. Others are the result of industrial processes. Including plastic manufacture and disposal

In May 1995, the United Nations Environment Programme Governing Council (GC) began investigating POPs. and 2001 the Stockholm Convention on Persistent Organic Pollutants was formed to organise the severe restriction of their production, by the international community.

State parties to the Stockholm Convention on P...

State parties to the Stockholm Convention on Persistent Organic Pollutants. Italiano: Stati ratificanti della Convenzione di Stoccolma sugli inquinanti organici persistenti. (Photo credit: Wikipedia)

These are related to the plastic industries

Dioxins

They are of concern because of their highly toxic potential.

Once dioxins have entered the body, they endure a long time because of their chemical stability and their ability to be absorbed by fat tissue, where they are then stored in the body.

Their half-life in the body is estimated to be seven to eleven years.

In the environment, dioxins tend to accumulate in the food chain. The higher in the animal food chain one goes, the higher the concentration of dioxins.

Doixin is a known human carcinogen and the most potent synthetic carcinogen ever tested in laboratory animals. Find out lots more here.

Dioxins occur as by-products in the incineration of chlorine-containing substances such as PVC (polyvinyl chloride), in the chlorine bleaching of paper, and from natural sources such as volcanoes and forest fires, waste incineration, and backyard trash burning, and herbicide manufacturing. More on burning plastic here.

Polychlorinated Biphenyls (PCBs) compounds are used as additives in paint, carbonless copy paper, and plastics.

Of the 209 different types of PCBs, 13 exhibit a dioxin-like toxicity. Their persistence in the environment corresponds to the degree of chlorination, and half-lives can vary from 10 days to one-and-a-half years.

PCBs are toxic to fish, killing them at higher doses and causing spawning failures at lower doses. Research also links PCBs to reproductive failure and suppression of the immune system in various wild animals, such as seals and mink.

Read more about PCBs here.

And here are some more…

Aldrin is an organochlorine insecticide that was widely used until the 1970s, when it was banned in most countries.

Chlordane a pesticide,  It was sold in the United States from 1948 to 1988, both as a dust and an emulsified solution. It is now banned.

DDT, First synthesized in 1874, DDT’s insecticidal action was discovered by the Swiss chemist Paul Hermann Müller in 1939.  A worldwide ban was formalised under the Stockholm Convention, but its limited use in disease vector control continues to this day and remains controversial.

Dieldrin  an alternative to DDT, and a highly effective insecticide widely used during the 1950s to early 1970s. Long-

term exposure has proven toxic to a very wide range of animals including humans.It is now banned in most of the world.

Endrin  A pesticide. Currently, the use of endrin is banned in many countries.

Heptachlor was used as an insecticide. Animals exposed to Heptachlor epoxide during gestation and infancy are found to have changes in nervous system and immune function. Higher doses of Heptachlor when exposed to newborn animals caused decrease in body weight and death.

Hexachlorobenzene, a fungicide now banned globally under the Stockholm Convention

Mirex, is a chlorinated hydrocarbon that was commercialized as an insecticide and later banned because of its impact on the environment.

toxaphene is an insecticide. It is a mixture of closely related substances whose use is now banned in most of the world due to concerns of toxicity.

Since then, this list has generally been accepted to include such substances as carcinogenic polycyclic aromatic hydrocarbons (PAHs) and certain brominated flame-retardants, as well as some organometallic compounds such as tributyltin (TBT).

Thanks to Wikipedia and the worldbank

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Dioxins

The chemical name for dioxin is: 2,3,7,8- tetrachlorodibenzo para dioxin (TCDD).

The name “dioxins” is often used for the family of structurally and chemically related polychlorinated dibenzo para dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs).

Certain dioxin-like polychlorinated biphenyls (PCBs) with similar toxic properties are also included under the term “dioxins”.

Some 419 types of dioxin-related compounds have been identified but only about 30 of these are considered to have significant toxicity, with TCDD being the most toxic.

Dioxins are classed as a persistant organic pollutants, (POPs), also known as PBTs (Persistent, Bioaccumulative and Toxic) or TOMPs (Toxic Organic Micro Pollutants.)

POPs are a small set of toxic chemicals that remain intact in the environment for long periods and accumulate in the fatty tissues of animals. You can find out more about POPS here

burning plastic & cow

Dioxins occur as by-products in  the incineration of chlorine-containing substances such as PVC (polyvinyl chloride), in the chlorine bleaching of paper, and from natural sources such as volcanoes and forest fires, waste incineration, and backyard trash burning, and herbicide manufacturing. More on burning plastic here

The most toxic chemical in the class is 2,3,7,8-tetrachlorodibenzo-para-dioxin (TCDD). The highest environmental concentrations of dioxin are usually found in soil and sediment, with much lower levels found in air and water.

The word “dioxins” may also refer to other similarly acting chlorinated compounds (see Dioxins and dioxin-like compounds).

Dioxins are of concern because of their highly toxic potential. Experiments have shown they affect a number of organs and systems. Once dioxins have entered the body, they endure a long time because of their chemical stability and their ability to be absorbed by fat tissue, where they are then stored in the body. Their half-life in the body is estimated to be seven to eleven years.

In the environment, dioxins tend to accumulate in the food chain. The higher in the animal food chain one goes, the higher the concentration of dioxins.

“Humans are primarily exposed to dioxins by eating food contaminated by these chemicals. Dioxin accumulates in the fatty tissues, where they may persist for months or years. People who have been exposed to high levels of dioxin have developed chloracne, a skin disease marked by severe acne-like pimples. Studies have also shown that chemical workers who are exposed to high levels of dioxins have an increased risk of cancer. Other studies of highly exposed populations show that dioxins can cause reproductive and developmental problems, and an increased risk of heart disease and diabetes. More research is needed to determine the long-term effects of low-level dioxin exposures on cancer risk, immune function, and reproduction and development.”

Doixin is a known human carcinogen and the most potent synthetic carcinogen ever tested in laboratory animals. A characterization by the National Institute of Standards and Technology of cancer causing potential evaluated dioxin as over 10,000 times more potent than the next highest chemical (diethanol amine), half a million times more than arsenic and a million or more times greater than all others.” From the World Health Organisation

“Dioxins, which are highly toxic even at low doses, are produced when plastics are manufactured and incinerated. While dioxin levels in the U.S. environment have been declining for the last 30 years, they break down so slowly that some of the dioxins from past releases will still be in the environment many years hence.

In its 2000 final draft reassessment of the health effects of dioxins, the EPA concluded that dioxins have the potential to produce an array of adverse health effects in humans. The agency’s report estimated that the average American’s risk of contracting cancer from dioxin exposure may be as high as one in 1,000–1,000 times higher than the government’s current “acceptable” standard of one in a million.

Dioxins are also endocrine disruptors, substances that can interfere with the body’s natural hormone signals. Dioxin exposure, moreover, can damage the immune system and may affect reproduction and childhood development.” The green guide

Dioxins are unintentionally, but unavoidably produced during the manufacture of plastics containing chlorine, including PVC and other chlorinated plastic feedstocks.

Halogenated plastics include:
Chlorine based plastics:
Chlorinated polyethylene (CPE)
Chlorinated polyvinyl chloride (CPVC)
Chlorosulfonated polyethylene (CSPE)
Polychloroprene (CR or chloroprene rubber, marketed under the brand name of Neoprene)
PVC
Fluorine based plastics:
Fluorinated ethylene propylene (FEP)

Burning these plastics can release dioxins. 

More on PVC here

More on burning plastic here

Other Sources

U.S. Department of Health and Human Services

Wikkipedia