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BPA

Bisphenol A or BPA is it is known to its chums is used in

  • some thermal paper products such as till receipts.
  • the epoxy plastic liners found in many cans and tins,
  • polycarbonate plastics used to make hard plastic for CDs, cell phones, car parts, medical devices, safety goggles
  • Plastic microwave oven ware, eating utensils and  bottles (including baby bottles).
  • Plastics  labelled with the number “7” identification code. HOWEVER not all plastics labelled with the number “7” contain BPA. The number “7” code is assigned to the “Other” category, which includes all plastics not otherwise assigned to categories 1-6.

The chemical was invented in the 1930s during the search for synthetic estrogens.  Diethylstilbestrol was found to be a more powerful estrogen, so bisphenol A was put to other uses. It was polymerized to form polycarbonate plastic and used to make a wide range of products including those listed above.

Over the years there have been an increasing number of claims that the polymer  is not stable. That, over time, BPA breaks down over time and releases hormones into whatever product it comes into contact with.  Research has indeed proved that  BPA can leach into food from the epoxy linings in cans or from polycarbonate bottles, and that the rate increases if the containers are heated i.e. babies bottle being sterilised or a tin being heated.

However additional studies are now suggesting that the ingestion of leached BPA could be harmful. In March 1998 for example a study in Environmental Health Perspectives (EHP) found that BPA simulates the action of estrogen when tested in human breast cancer cells. A more recent study published in EHP shows a significant decrease of testosterone in male rats exposed to low levels of BPA. The study concludes that the new data is significant enough to evaluate the risk of human exposure to BPA.

BPA is now considered by many to be  a hormone disruptor, a chemical that alters the body’s normal hormonal activity.

In the last 10-15 years that concerns have been raised over its safety, particularly during pregnancy and for young babies.

In April 2008, the United States Department of Health and Human Services expressed concerns about it.

The Canadian government have just banned listed it a toxic substance and banned it from being used in baby bottles.

The following chart was taken from the very informative and interesting Wikkipedia article but you can find the same information all over the internet

Low dose exposure in animals

Dose (µg/kg/day) Effects (measured in studies of mice or rats,descriptions (in quotes) are from Environmental Working Group)[104][105] Study Year
0.025 “Permanent changes to genital tract” 2005[106]
0.025 “Changes in breast tissue that predispose cells to hormones and carcinogens” 2005[107]
1 long-term adverse reproductive and carcinogenic effects 2009[76]
2 “increased prostate weight 30%” 1997[108]
2 “lower bodyweight, increase of anogenital distance in both genders, signs of early puberty and longer estrus.” 2002[109]
2.4 “Decline in testicular testosterone” 2004[110]
2.5 “Breast cells predisposed to cancer” 2007[111]
10 “Prostate cells more sensitive to hormones and cancer” 2006[112]
10 “Decreased maternal behaviors” 2002[113]
30 “Reversed the normal sex differences in brain structure and behavior” 2003[114]
50 Adverse neurological effects occur in non-human primates 2008[44]
50 Disrupts ovarian development 2009[77]

 

So why the hell is BPA still being used  you might ask – between  nervously checking your genital tract and belting the kids.

‘BPA is such an easy chemical to make and it’s so useful,’ explains Tamara Galloway, a professor in ecotoxicology at the University of Exeter, UK.  ‘It is made from very cheap ingredients – acetone and phenol – and it makes a nice, clear, rigid polycarbonate and is really useful for making epoxy resins. ” Via Chemistry World .

According toPlasticsEurope, an association representing European plastic manufacturers, polycarbonate technology contributed €37 billion to the EU in 2007. And they state that more than 550,000 jobs in the EU depend – either directly or indirectly – on the production and use of polycarbonate. Via Chemistry World .

Also the science is by no means conclusive. It has become something of a cause with consumer and green groups who are vociferous in their opposition. Media  reporting tends to concentrate on the negative aspects of any new reports. Yet several scientific panels, including the European Union’s Scientific Committee on Food, the National Toxicology Program and the Harvard Center for Risk Analysis, have all concluded that the claims that low doses of BPA affect human health have not (yet ), been substantiated. While accepting that animal testing has produced adverse results they can find no concrete evidence that humans will react the same way.

And even if they do, the amounts of BPA we ingest are so minimal as to be negligible.

In Europe, the tolerable daily intake for BPA is set at 0.05 milligrams per kilogram of body weight. This value is an estimate of the amount of a substance that can be ingested daily over a lifetime without appreciable risk. The figure was calculated in 2006 by the European Food Safety Authority (EFSA), who at the same time stated that intakes of BPA through food and drink, for adults and children, were well below this value.Via Chemistry World .

The current U.S. human exposure limit set by the EPA is 50 µg/kg/day.

Which means, as the BPA industry’s voice over at to bishenol-a.org puts it

“Based on the results of the SPI study, the estimated dietary intake of BPA from can coatings is less than 0.00011 milligrams per kilogram body weight per day. This level is more than 450 times lower than the maximum acceptable or “reference” dose for BPA of 0.05 milligrams per kilogram body weight per day established by the U.S. Environmental Protection Agency.”

Which means an adult would have to eat  230 kilograms  of canned food and beverages every day of their life to exceed the safe level of BPA set by the U.S. Environmental Protection Agency.

As the toxicologists love to say – it’s not the poison but the dose…..

However, what is certain  is that  BPA is a $6 billion plus global industry. According to the National Institute of Health, approximately 940,000 tons of BPA are produced in the U.S. per year. About 21% is used in epoxy resins and most of the rest goes to polycarbonate.

want to know more – this is another good read.

You can find reports, studies and media scares on BPA here

Plasticisers

  • are man-made organic chemicals;
  • They are added to plastic,to make it flexible, resilient and easier to handle:
  • They include endocrine disrupting and controversial phthalates:

Claims as to the number of plasticisers out there vary from  300 different types of plasticisers to approximately 50.  

Over the last 60 years more than 30,000 different substances have been evaluated for their plasticising properties. After meeting the rigorous performance, cost, availability, health and environmental requirements which are imposed by the market, users and regulators only 50 are in use.

The most common plasticisers include esters such as adipates, azelates, citrates, benzoates, orthophthalates, terephthalates, sebacates, and trimellitates.

In 1999, the global volume of plasticizers was approximate 10 billion lbs, or about $5 billion.The market has an average yearly growth rate of 2-3%.

Of the ester plasticizers, standard phthalate esters comprise over 85% or the tonnage produced every year. They command the market due to their low cost and easy availability. Other common plasticizers include specialty phthalate esters, adipates, and trimellitates (which are used for low-temperature applications).

Over 90% of the plasticizer volume produced every year goes into Poly(Vinyl Chloride), or PVC. This polymer is found in anything from food packaging to construction materials to toys to medical

Category Name Accronym Used in Classified
Acetate Hexanedioic acid, polymer with 1,2-propanediol, acetate Film and sheet, Food packaging – Cling Wrap
Adipates Di isobutyl adipate (DIBA) DIBA Not class.
Adipates Di-2-ethylhexyl adipate (DEHA) DEHA Flooring, Wall coverings, Cladding and Roofing, Film and sheet, Automotive , Tubes & Hoses, Coated Fabrics, Inks and waxes, Food packaging – Cling Wrap, Toys Not class.
Adipates Di-isodecyl adipate (DIDA) DIDA Not class.
Adipates Di-isononyl adipate (DINA) DINA Adhesives & Sealants, Food packaging – Cling Wrap Not class.
Adipates Di-tridecyl adipate (DTDA) DTDA Not class.
Azelates Di-2-ethylhexyl azelate (DOZ) DOZ Not class.
Azelates Di-isodecyl azelate (DIDA) DIDA Automotive , Adhesives & Sealants
Benzoate Di-ethylene glycol dibenzoate Flooring Not class.
Benzoate Di-propylene glycol dibenzoate Flooring No harmonised C&L
Benzoate Isodecyl Benzoate (IDB) IDB Flooring, Wall coverings, Automotive , Adhesives & Sealants, Inks and waxes No harmonised C&L
Benzoate Isononyl Benzoate (INB) INB Not class.
Benzoate Isononyl Benzoate (INBB) INBB Flooring, Film and sheet Not class.
Benzoate Tri-ethylene glycol dibenzoate
Citrates acetyl tributyl citrate Food packaging – Cling Wrap, Toys, Medical Applications
Citrates acetyl triethyl citrate Not class.
Citrates tri-2-ethylhexyl citrate Not class.
Citrates tributyl citrate Not class.
Citrates triethyl citrate Not class.
Cyclohexanoate Di-isononyl cyclohexane dicarboxylate (DINCH) DINCH Flooring, Wall coverings, Film and sheet, Automotive , Adhesives & Sealants, Tubes & Hoses, Coated Fabrics, Food packaging – Cling Wrap, Toys, Medical Applications Not class.
ESO epoxidised linseed oil (ELO) ELO Not class.
ESO epoxidized soybean oil (ESBO) ESBO Automotive , Food packaging – Cling Wrap Not class.
Ester 1,2,3-Propanetricarboxylic acid, 2-(1-oxobutoxy)-trihexyl ester (BTHC) BTHC Medical Applications
Ester 2,2′-ethylenedioxydiethyl-bis-(2-ethylhexanoate) Film and sheet
Ester Alkylsulphonic acid ester with phenol (ASE) ASE Adhesives & Sealants, Food packaging – Cling Wrap, Toys No harmonised C&L
Ester Hexanedioic acid, polymer with 1,2-propanediol, octyl ester Film and sheet, Food packaging – Cling Wrap
Ester Hexanedioic acid, polymer with 2,2-dimethyl-1,3-propanediol and 1,2-propanediol, isononyl ester Film and sheet, Food packaging – Cling Wrap
Ester Isosorbide Diesters Flooring, Food packaging – Cling Wrap
Ester Pentaerythritol ester of valeric acid Flooring, Automotive , Toys
Ester TXIB (2,2,4-trimethyl-1,3pentanediol di-isobutyrate) TXIB Flooring, Adhesives & Sealants, Toys
Glycerol ester Fully acetylated monoglyceride Food packaging – Cling Wrap, Toys, Medical Applications Not class.
Orthophthalate Benzyl 3-isobutyryloxy-1-isopropyl-2,2-dimethylpropyl phthalate Coated Fabrics
Orthophthalate Benzyl butyl phthalate (BBP) BBP Flooring Repr. 1B Aquatic acute 1 Aquatic chronic 1
Orthophthalate Benzyl C7-9-branched and linear alkyl phthalate Flooring, Adhesives & Sealants
Orthophthalate bis(2-ethylhexyl) phthalate (DEHP) DEHP Repr. 1B
Orthophthalate Butyl cyclohexyl phthalate (BCP) BCP Not class.
Orthophthalate Butyl decyl phthalate (BDP) BDP Not class.
Orthophthalate Di(2-Propyl Heptyl) phthalate (DPHP) DPHP Flooring, Wall coverings, Cladding and Roofing, Cables and wires, Film and sheet, Automotive , Tubes & Hoses, Coated Fabrics Not class.
Orthophthalate Di(n-octyl) phthalate (DNOP) DNOP Not class.
Orthophthalate Di-C16-18 alkyl phthalate Cables and wires
Orthophthalate Di-isotridecyl phthalate
Orthophthalate Di-n-butyl phthalate (DBP) DBP Flooring, Automotive , Inks and waxes Repr. 1B Acute aquatic 1

 

Orthophthalate Di-n-hexyl phthalate (DNHP) DNHP No harm. C&L RAC opinion: Repr. 1B; H360FD
Orthophthalate Di-n-pentyl phthalate (DNPP) DNPP Repr. 1B Aquatic acute 1
Orthophthalate Di-n-propyl phthalate (DPP) DPP No harmonised C&L
Orthophthalate Diallyl phthalate (DAP) DAP Acute tox. 4 Aquatic acute 1 Aquatic chronic 1
Orthophthalate Dicyclohexyl phthalate (DCHP) Flooring, Toys No harm. C&L Reg.of intention: Repr. 1B; H360FD Skin Sens. 1; H317
Orthophthalate Diethyl phthalate (DEP) DEP Not class.
Orthophthalate Diisobutyl phthalate (DIBP) DIBP Automotive , Adhesives & Sealants, Inks and waxes Repr. 1B
Orthophthalate Diisodecyl phthalate (DIDP) DIDP Flooring, Cladding and Roofing, Cables and wires, Film and sheet, Automotive , Tubes & Hoses, Coated Fabrics, Inks and waxes Not class.
Orthophthalate Diisoheptyl phthalate (DIHP) DIHP Repr. 1B
Orthophthalate Diisohexyl phthalate (DHP) DHP RAC opinion: Repr. 1B, H360FD
Orthophthalate Diisononyl phthalate (DINP) DINP Flooring, Wall coverings, Cladding and Roofing, Cables and wires, Film and sheet, Automotive , Tubes & Hoses, Coated Fabrics, Inks and waxes Not class.
Orthophthalate Diisooctyl phthalate (DIOP) DIOP No harmonised C&L
Orthophthalate Diisotridecyl phthalate (DTDP) DTDP Cables and wires, Automotive Not class.
Orthophthalate Diisoundecyl phthalate (DIUP) DIUP Cladding and Roofing, Cables and wires, Automotive Not class.
Orthophthalate Dimethyl phthalate (DMP) DMP Not class.
Orthophthalate Ditridecyl phthalate (DTDP) DTDP Not class.
Orthophthalate Diundecyl phthalate (DUP) DUP Cladding and Roofing, Cables and wires Not class.
Orthophthalate n-Octyl n-decyl phthalate (ODP) ODP Not class.
Phosphate ester 2-ethyhexyl diphenyl phosphate Not class.
Phosphate ester TPP (Triphenyl phosphate) TPP Flooring, Wall coverings
Phosphate ester Tris (2-ethylhexyl) phosphate Not class.
Sebacates Di-2-ethylhexyl sebacate (DOS) DOS Not class.
Sebacates Di-isodecyl Sebacate (DIDS) DIDS Not class.
Sebacates Dibutyl sebacate (DBS) DBS
Sebacates Dimethyl sebacate (DMS) DMS Adhesives & Sealants
Terephthalate Di iso Butyl terephthalate (DBT) DBT Adhesives & Sealants Not class.
Terephthalate Di octyl terephthalate (DOTP or DEHTP) DOTP Flooring, Food packaging – Cling Wrap, Toys, Medical Applications Not class.
Trimellitate Tris-2-ethyhexyl trimellitate Cables and wires, Film and sheet, Medical Applications Not class.

Most Common Phthalates In Use (Wikkipedia)

Name Abbreviation Structural formula Molecular weight (g/mol) CAS No.
Dimethyl phthalate DMP C6H4(COOCH3)2 194.18 131-11-3
Diethyl phthalate DEP C6H4(COOC2H5)2 222.24 84-66-2
Diallyl phthalate DAP C6H4(COOCH2CH=CH2)2 246.26 131-17-9
Di-n-propyl phthalate DPP C6H4[COO(CH2)2CH3]2 250.29 131-16-8
Di-n-butyl phthalate DBP C6H4[COO(CH2)3CH3]2 278.34 84-74-2
Diisobutyl phthalate DIBP C6H4[COOCH2CH(CH3)2]2 278.34 84-69-5
Butyl cyclohexyl phthalate BCP CH3(CH2)3OOCC6H4COOC6H11 304.38 84-64-0
Di-n-pentyl phthalate DNPP C6H4[COO(CH2)4CH3]2 306.40 131-18-0
Dicyclohexyl phthalate DCP C6H4[COOC6H11]2 330.42 84-61-7
Butyl benzyl phthalate BBP CH3(CH2)3OOCC6H4COOCH2C6H5 312.36 85-68-7
Di-n-hexyl phthalate DNHP C6H4[COO(CH2)5CH3]2 334.45 84-75-3
Diisohexyl phthalate DIHxP C6H4[COO(CH2)3CH(CH3)2]2 334.45 146-50-9
Diisoheptyl phthalate DIHpP C6H4[COO(CH2)4CH(CH3)2]2 362.50 41451-28-9
Butyl decyl phthalate BDP CH3(CH2)3OOCC6H4COO(CH2)9CH3 362.50 89-19-0
Di(2-ethylhexyl) phthalate DEHP, DOP C6H4[COOCH2CH(C2H5)(CH2)3CH3]2 390.56 117-81-7
Di(n-octyl) phthalate DNOP C6H4[COO(CH2)7CH3]2 390.56 117-84-0
Diisooctyl phthalate DIOP C6H4[COO(CH2)5CH(CH3)2]2 390.56 27554-26-3
n-Octyl n-decyl phthalate ODP CH3(CH2)7OOCC6H4COO(CH2)9CH3 418.61 119-07-3
Diisononyl phthalate DINP C6H4[COO(CH2)6CH(CH3)2]2 418.61 28553-12-0
Di(2-propylheptyl) phthalate DPHP C6H4[COOCH2CH(CH2CH2CH3)(CH2)4CH3]2 446.66 53306-54-0
Diisodecyl phthalate DIDP C6H4[COO(CH2)7CH(CH3)2]2 446.66 26761-40-0
Diundecyl phthalate DUP C6H4[COO(CH2)10CH3]2 474.72 3648-20-2
Diisoundecyl phthalate DIUP C6H4[COO(CH2)8CH(CH3)2]2 474.72 85507-79-5
Ditridecyl phthalate DTDP C6H4[COO(CH2)12CH3]2 530.82 119-06-2
Diisotridecyl phthalate DIUP C6H4[COO(CH2)10CH(CH3)2]2 530.82 68515-47-9

 

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Oil from plastic…

Don’t throw those sweet wrappers away you may need them to run your car. They can be turned into oil by

  • Thermal depolymerization (TDP) or
  • Pyrolysis System.

Thermal Depolymerization 

is the thermal decomposition of organic compounds when heated to high temperatures in the presence of water. Organic compounds can mean anything from pig poop to plastic.

How it works….

Feedstock materials are first ground into small pieces and mixed with water. The mixture is then heated to 482°F (250°C) for approximately 15 minutes in a pressure vessel. The steam generated raises the pressure in the vessel to approximately 600 pounds per square inch (PSI) which, at the end of the heating process, is rapidly released. This causes the water to flash off or rapidly evaporate, thus leaving residual solids and crude hydrocarbons behind.

These constituents are separated and the hydrocarbons collected for further refinement. This involves further thermal treatment to 930°F (500°C) and fractional distillation sorting. The results are light and heavy naphthas, kerosene, and gas oil fractions which are suitable for the production of several grades of fuel oil. The residual solids remaining after the initial thermal treatment may be used as fertilizers, filters, soil fuels, and activated carbon for wastewater treatment. Wise Geek

It can be used in the recovery of PET, polyamides (except Nylon), and polyurethanes (except Styrofoam).

It mimics the natural geological processes thought to be involved in the production of fossil fuels. Under pressure and heat, the long chain polymers are broken down into short-chain petroleum hydrocarbons.

With thanks toWikipedia and Green Manufacturing 

Average TDP Feedstock Outputs[8]
Feedstock Oils Gases Solids (mostly carbon based) Water (Steam)
Plastic bottles 70% 16% 6% 8%
Medical waste 65% 10% 5% 20%
Tires 44% 10% 42% 4%
Turkey offal 39% 6% 5% 50%
Sewage sludge 26% 9% 8% 57%
Paper (cellulose) 8% 48% 24% 20%

(Note: Paper/cellulose contains at least 1% minerals, which was probably grouped under carbon solids.) Wikipedia

Pyrolysis

This company, Cynar,  use pyrolysis to turn plastic into oil. Here’s what they have to say on the subject

Suitable end of life plastics are preprocessed to size reduce and remove any contaminants or non-plastic materials from the feedstock at the first stage of the Cynar Technology. The shredded plastics and are then loaded via a hot melt in-feed system directly into main pyrolysis chambers. Agitation commences to even the temperature and homogenise the feedstocks. Pyrolysis then commences and the plastic becomes a vapour. Non-plastic materials fall to the bottom of the chamber.

The vapour from the chambers passes into the contactor which knocks back the long chained carbons and allows the required condensable vapours to pass into the distillation column. The system diverts the non-condensable synthetic gas through a scrubber and then back into the furnaces to heat the pyrolysis chambers. The condensable vapours are converted in the distillation column to produce lite oil and raw diesel. The lite oil is put into storage. The raw diesel is passed to the vacuum distillation column to be further refined to produce diesel, kerosene and lite oil; the distillates then pass into the recovery tanks.

The pyrolysis system is the prime chamber, which performs the essential functions of homogenisation and controlled decomposition in a single process. The Cynar Technology process requires minimal maintenance and produces a consistent quality distillate from end of life plastic.

Taken from the website

Wikkipedia has this to say on the subject.

Anhydrous pyrolysis can also be used to produce liquid fuel similar to diesel from plastic waste, with a higher cetane value and lower sulphur content than traditional diesel.[15] Using pyrolysis to extract fuel from end-of-life plastic is a second-best option after recycling, is environmentally preferable to landfill, and can help reduce dependency on foreign fossil fuels and geo-extraction.[16] Pilot Jeremy Roswell plans to make the first flight from Sydney to London using diesel fuel from recycled plastic waste manufactured by Cynar PLC.

Japan

Blest Technology based in Japan will sell you a machine to do it yourself at home .As the process sounds exactly like the one above  I am guessing it’s a pyrolysis based system.

Recyclable plastics are polypropylene (PP), polyethylene (PE) and polystyrene (PS). They cannot recycle PET.

“Teaching this at schools is the most important work that I do,” Ito reflects. In Japan too, he visits schools where he shows children, teachers and parents how to convert the packaging and drinking straws leftover from lunch.

If we were to use only the world’s plastic waste rather than oil from oil fields, CO2 emissions could be slashed dramatically, he says.

“It’s a waste isn’t it?” Ito asks. “This plastic is every where in the world, and everyone throws it away.” quoted here

“The carbon-negative system  is a highly-efficient technology, converting 1 kilogram (about 2 lbs.) of plastic into 1 liter (about a quart) of oil using just 1 kilowatt of power (cost: about .20 cents).

Of course, the end product of this conversion system is still fuel that must be burned, and thus, it will give off CO2 as part of the combustion process.  Read more here

Ocean Ambassadors promote its use.

It is in operation in over 80 countries worldwide, and has a processing capability of up to 20 tons a day.There are pilot projects in works from various universities as well as the UNDP.

We advocate and educate on this technology as a solution to island nations as it provides a real-time solution to effectively processing these “waste materials” locally and providing an end product that has a high demand in all locations.

As it is a low-sulfur burning content fuel and recorded as environmentally friendlier than standard diesel, we feel this technology offers us an option for the time being before we phase into plastic alternatives that are bio-based.

Homemade

Or you can build your own machine in your back yard like this guy!

 

Projects that look interesting

The Waste Combuster

Plastic is first processed in an upper tank, which converts the material into gas through a process called pyrolysis. Then, the gas moves to the lower tank, where it’s burned with oxidants. That burning generates heat and steam, which drive combustion and generate electric power. While other waste-to-fuel generators have been developed, Levendis says his machine has the added bonus of not producing harmful emissions.

The waste combustor is currently still in prototype phase, but Levendis is dreaming big: Eventually, he envisions scaling up this concept to juice a large power plant. A connected plastic recycling center could provide a constant stream of fuel.

India

Heres a plant in India thats transforming plastic into motorbike fuel  They say of the process that it “converts all sorts of waste plastic into fuel oil, petroleum gas and solid petroleum coke. It can work with all kinds of plastic waste, and doesn’t need the waste to be cleaned first. A fractional residue containing metals is the only possibly harmful by-product.”

Pretty sure that is thermal depolymerization

Talking of which .. I got this comment to one of my posts

If there is anybody who seriously wants an eco-friendly disposal system for used plastics, please contact me for this existing zero percent emission process technology that converts plastics into EN590 Diesel – ready for use in vehicles and other uses such as power generation.

Contact:  Mr. Anvi Arcilla

E-Mail: anvi@greenerpowersolutions.com

America

And the yanks are doing it too. This company in America are setting up a business that they hope will turn a profit in 15 months

More

Other ways to recycle plastic can be found here

And more ways to dispose of plastic here

 

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Bioplastics

Bioplastics or organic plastics are derived from renewable sources such as starch, vegetable oil and even chicken feathers.
Some plant derived plastics biodegrade, some do not.

The term bio-plastics is used to describe both types of plant derived plastic i.e. biodegradable and biomass derived.

This has led to some CONFUSION as some now think all bioplastics, biodegrade.
Not so.
Some bioplastics, like PLA plastic do biodegrade, indeed are certified compostable. 
Others, like the plant derived PET plastic, do not biodegrade.

Plant Derived PET
Ethane can be derived from plants.This is the same as ethane derived from oil and is used in the same way to make the same PET plastics.
Plant derived PET shares the same long-lasting, non-biodegradable qualities as petroleum derived PET i.e lasts pretty much forever.

Sorts Of Bioplastics

  • Cellulose derived plastics such as Cellophane. These plant derived plastics are amongst the first examples of the product and do biodegrade. ­
  • Starch based plastics which are compostable such as PLA plastics. They are certified compostable and do biodegrade.
  • Polyhydroxyalkanoates or PHAs  are linear polyesters produced in nature by bacterial fermentation of ­sugar or lipids. They are produced by the bacteria to store carbon and energy. They do biodegrade
  • chicken feathers bioplastic – biodegrades.
  • Ethane based plastics as used Coca-Cola’s PlantBottle which replaces 30 percent of the ethanol in their normal polyethylene terephthalate (PET) plastic bottle with 30 percent plant-derived ethanol. This means the bottle is still considered PET and can be recycled but is NOT biodegradable.

In short, just because a plastic has been made from plants does not mean it is biodegradable.

Useful To Know
The case for and against plant derived PET plastics – great article here
Why most plastics don’t biodegrade
What is Ethane .

Biodegradable/ degradable plastics.

Some conventional plastics are labeled biodegradable which may lead you to think they are, well, biodegradable! They are not. They have an additive that makes the plastic fall apart, degrade, more quickly. And only in certain conditions. You can read more here

 

Polystyrene

Polystyrene is used to make

  • coffee cups
  • soup bowls and salad boxes
  • foam egg cartons; produce & meat trays
  • disposable utensils
  • packing “peanuts”
  • foam inserts that cushion new appliances and electronics
  • television and computer cabinets
  • compact disc “jewel boxes” and audiocassette cases

It is also used as a building material, with electrical appliances (light switches and plates), and in other household items.

Polystyrene (Styrofoam in the USA) is a strong plastic created from erethylene and benzine that can be injected, extruded or blow molded, making it a very useful and versatile manufacturing material.Read more here
Styrene is primarily a synthetic chemical that is used extensively in the manufacture of plastics, rubber, and resins. It is also known as vinylbenzene, ethenylbenzene, cinnamene, or phenylethylene.

Derived from petroleum and natural gas by-products, styrene helps create thousands of remarkably strong, flexible, and light-weight products that represent a vital part of our health, safety and well-being. Probably the most recognizable material is polystyrene, often encountered as expanded polystyrene foam (EPS). Other styrene-based materials include acrylonitrile-butadiene styrene (ABS), styrene-acrylonitrile (SAN), styrene-butadiene rubber (SBR), and unsaturated polyester resin (UPR), which is better known as fiberglass. The styrene information and research center

Thousands of small units of styrene, called monomers, link together to form large molecules of polystyrene by a process called polymerisation.

Expanded polystyrene starts as small spherical beads with a typical diameter of 0.5-1.5mm. They contain an expanding agent;When the beads are heated with steam, the agent starts to boil, the polymer softens and the beads expand to about forty times their initial size. After a maturing period to equilibrate temperature and pressure, the pre-foamed beads, which now have a closed cellular foam structure, are placed in a mould and again reheated with steam. The mould can be designed to meet any requirements of the customer. The pre-foamed beads expand further, completely fill the mould cavity and fuse together. When moulded, nearly all the volume of the EPS foam (in fact 98%) is air. This is what makes EPS so lightweight and buoyant.

Taken from the styromelt website

It contains styrene which is according to some is  a toxic carcinogen that  leaches  from the container into the contents – your coffee for example – try this site for an in depth discussion of the issue.

The styrene information and research center ( representing the industy) has this to say on the subject “in 1989 OSHA and the U.S. Centers for Disease Control and Prevention’s National Institute for Occupational Safety and Health (NIOSH) reviewed the health data on styrene and concluded that styrene does not pose any cancer risk. An international panel of experts from the 12-nation European Community reached the same conclusion in 1988. Canada decided in 1994 that styrene posed no carcinogenic risk. A draft 1996 risk assessment of styrene by the Health & Safety Executive of the United Kingdom also concluded that styrene does not pose a carcinogenic threat.

In 1987, the International Agency for Research on Cancer (IARC) upgraded styrene’s classification to a “possible” human carcinogen. Many scientists have disputed this action because it was not based on new cancer data, but resulted from changes in the criteria for IARC classifications. ”

However it is on the hazardous substances list

REASON FOR CITATION
* Styrene Monomer is on the Hazardous Substance List because it
is regulated by OSHA and cited by ACGIH, NIOSH, DOT, DEP, NFPA
and EPA.
* This chemical is also on the Special Health Hazard Substance
List because it is a MUTAGEN, FLAMMABLE, and REACTIVE.

Safe levels of exposure have to be maintained and OSHA  also state “Health effects of styrene include irritation of the skin, eyes, and the upper respiratory tract. Acute exposure may also result in gastrointestinal effects. Chronic exposure affects the central nervous system showing symptoms such as depression, headache, fatigue, weakness, and may cause minor effects on kidney function. ”

Styrene is listed by the EU as a potential endocrine disruptor.

As with all plastics it  lasts an incredibly long time. Consequently plastic cups and clam shells can be seen littering the environment the world over.

Microplastic Polution

Tiny polystyrene globules from degraded products mix forever with the sand.

In the old days in couldnt be recyled; now it can but facilities are limited. Though of course that may well change in the future.

As with all plastic polystyrene does not biodegrade. Instead it hangs around for years creating everlasting litter and problomatic pollution. BUT the boffs are working on the problem and here are their solutions

Recycling

Polystyrene is difficult to recycle. Difficult but not impossible …

For those of you who insist on using polystyrene cups you can out more about recycling them here.

For the other stuff there is a  process for recycling  polystyrene that uses  the styromelt system.

 

Polystyrene and the OZONE LAYER

There are other issues with polystyrene the expanding agent that causes the styrene to puff up affects the ozone layer

However, despite EPF’s popularity and unique features, it has recently come under attack because of the gaseous methane derivatives—chlorofluorocarbons (CFCs)—used to foam it. CFCs are inert, and harmless to humans and the environment upon their release. However, long after their first use, scientists realized that CFCs contribute to the depletion of the ozone layer as they decompose. The ozone layer is a layer of the atmosphere that protects the earth against harmful ultraviolet rays from the sun. In 1988 representatives from 31 nations signed the Montreal Protocol, a treaty with which they resolved to halve CFC production by 1998. This agreement brought EPF to the world’s consciousness as a threat to the ozone layer. While foam packaging is responsible for less than three percent of the CFCs being released into the atmosphere, EPF reduction has been targeted as a way to lower CFC levels, and new technology that explores ways to produce EPF without CFCs has flourished.

see  answers website

the expanding agent now used is “a pure hydrocarbon, which does not contain any halogens and does not damage the earth’s protective ozone layer.” Taken from the styromelt website

However environmentalists disagree see rebuttal

As with all plastic the arguments are split between the producers and the environmentalists and can be very basically summarised as follows: superlative product with a myriad of wonderful applications, recyclable and above all completely inert and safe as opposed to consumerism gone mad and leacher of carcinogenic chemicals.

But whichever your school of thought all agree that its looks nasty, is polluting the environment and lasts a very long time. So lets not use it to make throw away items.

Nylon

Nylon is often associated with the fabric of the same name but can be used to make all manner of things from fibre to  moulded objects.

Different nylon types are known by their numbers e.g. Nylon 6,6; Nylon 6,12; Nylon 4,6; Nylon 6; Nylon 12 etc

It is a polyamide plastic typified by amide groups (CONH)

Wallace Carothers at the Dupont Chemical company  discovered polyamides in 1931. On the 28th October 1938 commercial production of nylon 6,6 began.

Interestingly it was  first used to make the bristles on Dr West’s Miracle Tuft toothbrush.

But nylon is really synonymous with stockings.

On October 27, 1938, Charles Stine, vice president of Du Pont,announced that nylon had been invented. Unveiling the world’s first synthetic fiber not to a room full of corporates or scientists but to the three thousand strong women’s club members who were gathered at the site of the New York World’s Fair for the New York. He exclaimed ” nylon can be fashioned into filaments as strong as steel, as fine as a spider’s web, yet more elastic than any of the common natural fibers.” Thinking that “strong as steel” meant indestructible stockings, the women at the forum burst into applause.

Commercial production of nylon stockings began in 1939, and by the end of 1940 over 64 million pairs had been sold.

But the outbreak of World War 2 meant nylon had to be used for other more military things.

“The strength of nylon comes from amide groups in its molecular chain, which bond together very well. It also has a very regular shape, which makes it well suited to creating fabrics designed to stand up to intense forces.”  This made it ideal for the parachutes and ropes needed in war times. It is still  used now  for bulletproof vests and other hard-wearing items.

In 1941, nylon moulding powders began commercial production but nylon mouldings were not widely used until the 1950’s.

Today nylon fibres are used in textiles, fishing line and carpets. It is the second most used fiber in the United States.

Nylon films are used for food packaging. Because it can resist intense heat it is ideal for  boil-in-the-bag meals. Ugh!

Moulding and extrusion compounds find many applications as replacements for metal parts, for instance in car engine components. Intake manifolds in nylon are tough, corrosion resistant, lighter and cheaper than aluminium (once tooling costs are covered) and offer better air flow due to a smooth internal bore instead of a rough cast one. Its self-lubricating properties make it useful for gears and bearings.Electrical insulation, corrosion resistance and toughness make nylon a good choice for high load parts in electrical applications as insulators, switch housings and the ubiquitous cable ties. Another major application is for power tool housings.

Biodegradability

On the whole nylon, like most petroleum products, is not considered to be  biodegradable which means the accumulation of  an awful lot of trash.

For example an estimated £100 million worth (based on 2015 prices) or around 350,000 tonnes of used clothing goes to landfill in the UK every year . At least 60% f that will be synthetic fibres.

Degrading

But it seems ( according to Wikkipedia),  that Nylon 4 or polybutyrolactam can be degraded by the (ND-10 and ND-11) strands of Pseudomonas sp. found in sludge. This produces γ-aminobutyric acid (GABA) as a byproduct.[1]Nylon 4 is thermally unstable.[2]

Studies

The nylon4 portion in the blend films composed of nylon4 and nylon6 was degraded and completely disappeared within 4 months in two kinds of composted soils gathered from different university farms as well as pure nylon4 film reported previously, while the nylon6 portion remained even after the burial test for 15 months. Nylon4 powder was also degraded to carbon dioxide in the degradation test in an activated sludge obtained from a sewage disposal institution in Kogakuin University. Three species of microoganisms (i.e., ascomytous fungi) were isolated through the inoculation from the nylon4 film partially degraded in the soil on a medium containing nylon4 powder as a carbon source. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2307–2311, 2002

 

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Dioxins

The chemical name for dioxin is: 2,3,7,8- tetrachlorodibenzo para dioxin (TCDD).

The name “dioxins” is often used for the family of structurally and chemically related polychlorinated dibenzo para dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs).

Certain dioxin-like polychlorinated biphenyls (PCBs) with similar toxic properties are also included under the term “dioxins”.

Some 419 types of dioxin-related compounds have been identified but only about 30 of these are considered to have significant toxicity, with TCDD being the most toxic.

Dioxins are classed as a persistant organic pollutants, (POPs), also known as PBTs (Persistent, Bioaccumulative and Toxic) or TOMPs (Toxic Organic Micro Pollutants.)

POPs are a small set of toxic chemicals that remain intact in the environment for long periods and accumulate in the fatty tissues of animals. You can find out more about POPS here

burning plastic & cow

Dioxins occur as by-products in  the incineration of chlorine-containing substances such as PVC (polyvinyl chloride), in the chlorine bleaching of paper, and from natural sources such as volcanoes and forest fires, waste incineration, and backyard trash burning, and herbicide manufacturing. More on burning plastic here

The most toxic chemical in the class is 2,3,7,8-tetrachlorodibenzo-para-dioxin (TCDD). The highest environmental concentrations of dioxin are usually found in soil and sediment, with much lower levels found in air and water.

The word “dioxins” may also refer to other similarly acting chlorinated compounds (see Dioxins and dioxin-like compounds).

Dioxins are of concern because of their highly toxic potential. Experiments have shown they affect a number of organs and systems. Once dioxins have entered the body, they endure a long time because of their chemical stability and their ability to be absorbed by fat tissue, where they are then stored in the body. Their half-life in the body is estimated to be seven to eleven years.

In the environment, dioxins tend to accumulate in the food chain. The higher in the animal food chain one goes, the higher the concentration of dioxins.

“Humans are primarily exposed to dioxins by eating food contaminated by these chemicals. Dioxin accumulates in the fatty tissues, where they may persist for months or years. People who have been exposed to high levels of dioxin have developed chloracne, a skin disease marked by severe acne-like pimples. Studies have also shown that chemical workers who are exposed to high levels of dioxins have an increased risk of cancer. Other studies of highly exposed populations show that dioxins can cause reproductive and developmental problems, and an increased risk of heart disease and diabetes. More research is needed to determine the long-term effects of low-level dioxin exposures on cancer risk, immune function, and reproduction and development.”

Doixin is a known human carcinogen and the most potent synthetic carcinogen ever tested in laboratory animals. A characterization by the National Institute of Standards and Technology of cancer causing potential evaluated dioxin as over 10,000 times more potent than the next highest chemical (diethanol amine), half a million times more than arsenic and a million or more times greater than all others.” From the World Health Organisation

“Dioxins, which are highly toxic even at low doses, are produced when plastics are manufactured and incinerated. While dioxin levels in the U.S. environment have been declining for the last 30 years, they break down so slowly that some of the dioxins from past releases will still be in the environment many years hence.

In its 2000 final draft reassessment of the health effects of dioxins, the EPA concluded that dioxins have the potential to produce an array of adverse health effects in humans. The agency’s report estimated that the average American’s risk of contracting cancer from dioxin exposure may be as high as one in 1,000–1,000 times higher than the government’s current “acceptable” standard of one in a million.

Dioxins are also endocrine disruptors, substances that can interfere with the body’s natural hormone signals. Dioxin exposure, moreover, can damage the immune system and may affect reproduction and childhood development.” The green guide

Dioxins are unintentionally, but unavoidably produced during the manufacture of plastics containing chlorine, including PVC and other chlorinated plastic feedstocks.

Halogenated plastics include:
Chlorine based plastics:
Chlorinated polyethylene (CPE)
Chlorinated polyvinyl chloride (CPVC)
Chlorosulfonated polyethylene (CSPE)
Polychloroprene (CR or chloroprene rubber, marketed under the brand name of Neoprene)
PVC
Fluorine based plastics:
Fluorinated ethylene propylene (FEP)

Burning these plastics can release dioxins. 

More on PVC here

More on burning plastic here

Other Sources

U.S. Department of Health and Human Services

Wikkipedia

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Degradation Initiators & Degradable Plastic

Traditional plastics do not biodegrade. Of course plastic breaks, tears and cracks. It weathers and sunlight makes it brittle, It falls apart – it degrades – but only into smaller pieces of plastic. And that can take hundreds of years. See Why Plastic Doesn’t Rot.

Plastic litter is not surprisingly increasing exponentially with disastrous environmental consequences.

But suppose there was a way of making non-biodegradable plastic, biodegradable? The plastic industry argue that they can do just that by means of chemical adatives known as degradation initiators.

Types Of Degradable Plastics

The ISO (International Organization for Standardization) has defined six types of degradable plastics.

  • Degradable – breaks down in some way.
  • Photodegradable, broken down by light
  • Oxidatively degradable broken down by oxygen.
  • Hydrolytically degradable. Broken down by water
  • *Biodegradable – can be broken down by microbes to mass, water and co2 but with no indication of how long that might take. May also need chemical addatives to make this process possible.
  • *Compostable – degrade at a rate that’s similar to other types of compostable materials, and they result, again, in water, carbon dioxide, humus, and inorganic compounds. Compostable plastics biodegrade naturally.They do not need additonal addatives to break down the polymers as they made from natural materials that microorganisms recognise.

This is a confusing list because the last two (*) seem to refer to the natural process of biodegrading while the others refer to  plastic with added degradation initiators. It is important to note that there is a huge difference. Degradable does not mean biodegradable despite what the plastics industry tries to imply.

What Are Degradation Initiators

Degradation initiators are added to the plastic mix in amounts of up to 2% of the total composition. Very basically, these addatives break the long unnatural plastic polymers into shorter recognisable polymers that microbes can attack and digest – or biodegrade.

English: illustration of the Oxo-Bio-Degradati...

English: illustration of the Oxo-Bio-Degradation is, as the name describes, a two-step process whereby the conventional polyolefin plastic is first oxo-degraded to short-chain oxygenated molecules (typically 2-4 months exposed) and then biodegraded by the micro-organisms (Bacteria, Fungi, etc.). (Photo credit: Wikipedia)

The process happens as follows.

  • Microbes are attracted to the additive;
  • They “crack” the long polymer allowing acces to other microbes and water.
  • Eventually these will break down huge polymers into smaller and smaller bits.
  • These smaller bits are then vulnerableto other microbes.

More Research

That’s the theory and it sounds good BUT as Green Plastics point out

“you can add an additive to normal, petroleum-based plastic that will make it become brittle and crumble in sunlight: this is referred to as making “photodegradable” plastic. Other additives can be put into plastic that will make plastic break down by oxidation: this is referred to as making “oxo-degradable plastic.”

These methods will make the bulk of the plastic appear to disappear; however, the small pieces (or even find “sand”) that is produced by this effect is still small pieces of plastic.  Nothing has changed. Over a matter of years, it is possible for the pieces to become small enough to be assimilated by microorganisms, but there is still a lot of research that needs to be done to verify how long this might take.  In the mean time, they are just very small pieces of plastic.”

Or this by Eco Savvy

“The only difference between “oxo-biodegradable” plastic and petroleum based plastic is the presence of an oxo-formulated additive in concentrations of 1-3% (metal salts) within the petroleum based plastic.  This additive allows the petroleum based plastics to degrade in the presence of oxygen, light, heat and moisture.

Oxo-biodegradable plastic is designed to degrade in the open environment and this short timeframe of biodegradation is not necessary. Furthermore, a high rate of conversion is not desirable because the conversion to greenhouse gases such as carbon dioxide contribute to the warming of the atmosphere, hole in the ozone layer and depletion of carbon available for the soil.”

The Right Place At The Right Time

The difficulty is of course ensuring that the plastic doesn’t start biodegrading in normal conditions so that the strength of the plastic product is not jeopodised. Biodegradation is designed to start in certain extreme conditions.

As 75% ofplastic ends up in landfill, most addatives are designed to work in landfill conditions.

While products may start to degrade outside of  the specified conditions but the process will take much longer.

The obvious flaw in this solution is the wrong product in the wrong place. For example plastic that has been manipulated to degrade quickly in a landfill conditions ending up as litter on the roadside where it will not degrade quickly.

Other Considerations

So, to become degradable, plastic has to be further chemically engineered. Obviously, this is by no means a natural process (as biodegrading is normally understood to be), rather it requires complex chemical eginerring.

The composition of these chemical addatives is secret and known only to the companies who produce them.

Biodegradable plastics are made using traditional (usually petrochemical based) plastics. They don’t always break down into harmless substances.

Confusing & Misleading Marketing

Because the initiators are bio-based this has led to the process being described as bio degradable. .

Which has led to confusion because now bio -degradable plastic could be a compostable plastic that biodegrades naturally OR plastic that has had a degradation initiator added to make it bio-degrade.

Compostable plastic is a plastic that can biodegrade with out chemical addatives within a certain amount of time.

The Guardian reported in October 2014 that

Last month, the FTC sent warning letters to 15 additional marketers, informing them that their claims “may be deceptive”. The FTC also requested “competent and reliable scientific evidence proving that their bags will biodegrade as advertised”. This time, the term of offense is “oxodegradable”, implying the bag will break down in time when exposed to oxygen.

And

“The plastic is not degrading, it’s fragmenting,” Greene said. Over time, as opposed to breaking down into less hazardous organic components, these plastic products break down into lots of small, equally toxic bits.

Why make plastics degradable?

Why go to the effort of making degradable plastic bags when we already have naturally compostable products such as paper bags and cornstarch bags. Why not use plastic for things we don’t want to rot away like drainpipes and use naturally biodegrading materials for disposable packaging?

Useful stuff to know

Degradable, biodegradable or compostable plastics – whats in a name
Why leaves rot and why most plastics don’t at Why Plastic Doesnt Rot

Degradable, biodegradable or compostable

So most plastics are made from oil and most plastics do not biodegrade. See how and why here… And yet you will find plastics described as degradable ...
Read More

Compostable Plastics Index

Plastic was the name given to early synthetic products such as cellophane,  that were derived from cellulose. These plastics  were biodegradable. Then they learnt how to make ...
Read More

Biodegrading and degradation – Plastic Lifespan,

So most plastics are made from oil and most plastics do not biodegrade. See how and why here... But what does that actually mean? Biodegrading Biodegradation ...
Read More

Plastic eating microbes

Is this a good idea?- much as I hate bad plastic I am rather attached to the computer and Dyson. Will they disappear before my very eyes ...
Read More

Degradation Initiators & Degradable Plastic

Traditional plastics do not biodegrade. Of course plastic breaks, tears and cracks. It weathers and sunlight makes it brittle, It falls apart – it degrades – but ...
Read More

Trash Vortex / 5 Gyres

Dotted around the world are  5 great trash vortexes. They are right out there in the middle of the sea and they are huge.  A “plastic soup” of waste floating in the Pacific Ocean is growing at an alarming rate and now covers an area twice the size of the continental United States, is how scientists have described one such.

This drifting “soup” stretches from about 500 nautical miles off the Californian coast, across the northern Pacific, past Hawaii and almost as far as Japan.

And it now appears that there are 4 more.

They are called trash Votrexes or the 5 gyres.

What happens is swirling currents collect up all the ocean debris and mix it into a big rubbish soup in the centre of the ocean. In the old days this rubbish was biodegradable so would rot.

Not any more.

These days its plastic which does not rot.

Result a vast expanse of debris – in effect the world’s largest rubbish dump – is held in place by swirling underwater currents.

Is how the Independant newspaper describes it.

Though Greenpeace have been worried for a while

Why are there no photos? Oysters garter has the best answer

Dont fancy reading? Watch one of these scary videos of what lurks beneath the waves

For educational dvds go to http://www.algalita.org/videos-research.html

other articles to read on the subject are Naked man in the tree

 

 

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Plastic codes and UK recycling

Resin identification code 2 ♴ for high density...

Plastic codes are the numbers you find on the base of your shampoo bottle and the like.

They  identify the type of plastic used to make the product.

Only the most common types of plastic are numbered – there are many more plastics than numbers and new plastics are being made all the time.

This symbol DOES not mean the product has been recycled.

For recycling purposes, (for now at least), it is essential to know which plastic is which.

All plastics should be properly identified.

Here are the current plastic codes and what they refer to.

PET or PETE (Polyethylene terephthalate) plastic code 1
Clear drinks bottles, food packaging such as fruit punnets, textile fibres (polyester).

UK Collection Rates
PET bottles are collected by 92% of councils. Recycled PET is generally used in fabrics such as fleece, strapping and carpets. New technology allows PET to be recycled into new food packaging.

HDPE (High-density polyethylene) plastic code 2
Milk bottles, shampoo and cleaning product bottles. HDPE bottles are collected by 92% of councils.They are recycled into garden furniture, litter bins and pipes.

UK Collection Rates
New technology allows HDPE to be recycled into new milk bottles.

PVC (Polyvinyl chloride) plastic code 3
Window frames, drainage pipes, shower curtains, clothing, toys, large squash bottles.

UK Collection Rates
Not generally collected from households for recycling. PVC use in packaging is in decline.

LDPE (Low density polyethylene) plastic code 4
Carrier bags, some bottles and containers, yokes holding four or six-packs of cans together, lining or laminating cardboard containers.
Carrier bags are collected by some supermarkets and recycled into low-grade uses such as bin bags.

UK Collection Rates
Not generally collected from households for recycling. However, mixed plastic recycling is expected to be under way within five years.

PP (Polypropylene) plastic code 5
Soup pots, margarine tubs, most bottle tops, waterproof clothing, carrier bags.
Not generally collected for household recycling, although it has good potential.

UK Collection Rates
However, mixed plastic recycling is expected to be under way within five years.

PS (Polystyrene) plastic code 6
Take away cups, yoghurt pots, cushioning of breakable objects in packaging.

UK Collection Rates
Not generally collected from households for recycling. Some commercial polystyrene is recycled.

Everything else plastic code 7
Other Includes acrylic glass (perspex), nylon and polycarbonate. Items made from a blend of plastics also fall into this category.

UK Collection Rates

Not currently collected

The collection rates are taken from this BBC article

To know more about the above plastics go to everything you ever wanted to know about plastic

To find out where you can recycle each kind of plastic, contact your waste disposal authority, or check the internet. Some recycling plants will accept plastics from the public and are interested in bulk supply from anywhere.

But better still don’t create any plastic trash…..